As a result some of the precipitate returns back to separate Silver and Chloride ions. ... If we consider worst case scenario where the maximum amount of chloride ions dissolve and remain in the solution the following concept helps to calculate the solubility of the Chloride ions: For this reaction, each mole of AgCl that dissolves produces 1 mole of both Ag+  ions and Cl- ions. The solubility would then equal the concentration of either the Ag+ or Cl- ions. ... None the less if this photochemical decomposition happens in the presence of excess Silver ions in an aqueous solution the following...

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